Alchagirov B.B., Kyasova O.Kh., Kokov Z.A.
Kabardino-Balkaria State University name after H.M. Berbekov, Nalchik, Russia
Progress in the study of the surface and thermophysical properties of liquid metal coolants are deter-mined by the level of development and the state of the used experimental equipment and research tech-nology, as in the other areas of science. Therefore, the solution of the problem of further improving the existing and developing new methods and devices for studying the physical chemistry of highly active liquid metal coolants of the new generation with the participation of alkali metals that are promising for use in nuclear power engineering is relevant in this direction. A special place is occupied by the problem of creating automated experimental facilities designed to track and study the dynamics of high-speed processes on the surfaces under examination among them. The paper describes an experimental setup developed and tested by the authors with a software package that made it possible to automate the processes of measuring, collecting and processing significant arrays of primary data on the temperature dependences of the surface tension of metals and their alloys in the liquid state. It allows you to track rapid changes in the most important energy characteristics of the substance surface in the condensed state — surface tension, occurring during the flow of various physicochemical processes on the surfaces of liquid metal coolants under conditions of adsorption of molecules from the gas atmosphere. The results obtained by the method of a lying drop of comparative measurements of the surface tension of high purity mercury used as a test object, demonstrated high reliability and capabilities of the new automated installation. Measurements were carried out in continuous mode on the same sample surface, under high static vacuum and in atmospheres of various gases (dry air, nitrogen, oxygen, etc.).
1. Semenchenko V.K. Poverkhnostnyye yavleniya v metallakh i splavakh [Surface phenomena in metals and alloys]. Moscow, GITTL Publ., 1957. 491 p.
2. Rusanov A.I., Prokhorov V.A. Mezhfaznaya tenzometriya [Interfacial Tensimetry]. St. Petersburg, Khimiya Publ., 1994. 400 p.
3. Adamson A. Fizicheskaya khimiya poverkhnosti [Physical surface chemistry]. Moscow, Mir Publ., 1979. 568 p.
4. Roldugin V.I. Fizikokhimiya poverkhnosti [Physicochemistry of the surface]. Dolgoprudnyy, Intellekt Publ., 2008. 568 p.
5. Zadumkin S.N., Khokonov Kh.B., Alchagirov B.B., Karamurzov B.S., Taova T.M. Fizika mezhfaznykh yavleniy v kondensirovannykh sredakh [Interphase physics in condensed media]. Nalchik, Kabardino—Balkaria State University Publ., 2014. 247 p.
6. Yemelyanenko A.M., Boynovich L.B. Analiz smachivaniya kak effektivnyy metod izucheniya kharakteristik pokrytiy, poverkhnostey i proiskhodyashchikh na nikh protsessov (obzor) [Wetting analysis as an effective method for studying the characteristics of coatings, surfaces and the processes occurring on them (review)]. Zavodskaya laboratoriya. (Diagnostika materialov) - Factory laboratory. (Diagnostics of Materials), 2010, vol. 76, no. 9, pp. 27.
7. Alchagirov B.B., Kalazhokov Kh.Kh., Khokonov Kh.B. Sovremennyye metody izmereniy bystrykh izmeneniy raboty vykhoda elektrona [Modern methods for measuring the rapid changes in the electron work function]. Izvestiya Rossiyskoy Akademii Nauk: Seriya Fizicheskaya - Bulletin of the Russian Academy of Sciences: Physics, 1991, vol. 55, no. 12, pp. 2463.
8. Rusanov A.I., Levichev S.A., Zharov V.T. Poverkhnostnoye razdeleniye veshchestv. Teoriya i metody [Surface separation of substances. Theory and methods]. Leningrad, Khimiya Publ., 1981. 184 p.
9. Subbotin V.I., Arnoldov M.N., Kozlov F.A., Shimkevich A.L. Zhidkometallicheskiye teplonositeli dlya yadernoy energetiki [Liquid metal coolants for nuclear energy]. Atomnaya energiya - Atomic Energy, 2002, vol. 92, no. 1, pp. 31—41.
10. Alchagirov B.B., Dadashev R.Kh. Metod bol'shoy kapli dlya opredeleniya plotnosti i poverkhnostnogo natyazheniya metallov i splavov [Big Drop Method for Determination of Density and Surface Tension of Metals and Alloys]. Nalchik, KBGU Publ., 2000. 94 p.
11. Director L.B., Zaitchenko V., Maikov I.L. Usovershenstvovannyy metod lezhashchey kapli dlya opredeleniya poverkhnostnogo natyazheniya zhidkostey [An improved method of sessile drop for determining the surface tension of liquids]. Teplofizika vysokikh temperatur - High Temperature, 2010, vol. 48, no. 2, pp. 193.
12. Ivashchenko Yu.N., Yeremenko V.N. Osnovy pretsizionnogo izmereniya poverkhnostnoy energii rasplavov metodom lezhashchey kapli [Fundamentals of precision measurement of the surface energy of melts by the method of a lying drop]. Kiev, Naukova dumka Publ, 1972. 234 p.
13. Ivashchenko Yu.N., Bogatyrenko B.B., Yeremenko V.N. K voprosu o raschete poverkhnostnogo natyazheniya zhidkosti po razmeram lezhashchey kapli [On the question of calculating the surface tension of a liquid by the size of a lying drop]. Kiev, Naukova dumka Publ., 1963. P. 391.
14. Krinochkin E.V., Kurochkin K.T., Umrikhin P.V. K opredeleniyu poverkhnostnogo natyazheniya rasplavov metodom lezhashchey kapli [To the determination of the surface tension of melts by the method of a lying drop]. Kiev, Naukova dumka Publ., 1971. P. 69.
15. Ivashchenko Yu.N. Ob opredelenii poverkhnostnoy energii rasplavov po razmeram lezhashchey kapli [On the determination of the surface energy of melts by the size of a lying drop]. Kiev, Naukova dumka Publ., 1971. P. 75.
16. Kokov Z.A., Dyshekova F.F., Kokov A.A., Alchagirov B.B., Arkhestov R.Kh, Kegadueva Z.A. Programma avtomatizatsii fizicheskogo eksperimenta po izmereniyu PN zhidkostey metodom bol'shoy lezhashchey kapli [The program of automation of a physical experiment on the measurement of PN liquids by the method of a large lying drop]. Certificate of state registration of computer programs, no. 2015614191, 2015.
17. Canny J.F. A computational approach to edge detection. IEEE Trans. on Pattern Analysis and Machine Intelligence, 1986, vol. 8(6), pp. 679.
18. Prett U. Tsifrovaya obrabotka izobrazheniy [Digital image processing]. Moscow, Mir Publ., 1982. 790 p.
19. Dorsey N.E. A new equation for determination of the surface tension from the form a sessile drop or babble. Journal of the Washington Acad. of Sci., 1928, vol. 18, no. 19, pp. 505.
20. Alchagirov B.B., Kyasova O.Kh., Kokov Z.A., Uzdenova A.N. Avtomatizirovannaya ustanovka dlya izmereniya bystrykh izmeneniy poverkhnostnogo natyazheniya zhidkometallicheskikh teplonositeley [Automated installation for measuring rapid changes in the surface tension of liquid metal coolants]. Trudy nauchno-tekhnicheskoy konferentsii “Teplofizika reaktorov novogo pokoleniya (Teplofizika-2018)” [Proc. Sci. and Techn. Conf. "Thermophysics of Reactors of the New Generation (Thermophysics-2018)"]. Obninsk, 2018, pp. 40.