EDN: KIXHMW
Authors & Affiliations
Gonchar N.I.
A.I. Leypunsky Institute for Physics and Power Engineering, Obninsk, Russia
Gonchar N.I. – Leading Researcher, Cand. Sci. (Tech.), A.I. Leypunsky Institute for Physics and Power Engineering.
Contacts: 1, pl. Bondarenko, Obninsk, Kaluga region, Russia, 249033. Tel.: +7 (484) 399-42-59; e-mail: This email address is being protected from spambots. You need JavaScript enabled to view it.
Abstract
Heavy liquid metal coolant (HLMC) containing lead and bismuth form alpha-active isotopes: 210Po, 209Po and 210mBi. 210Po is the most radiotoxic one. Under normal operating conditions with gas-tight primary system, there is no radiation hazard caused by polonium. The hazard appiars in case of the primary circuit integrity loss which is possible in the course of scheduled repair work on the primary components, reactor refueling or in case of accident with radioactive coolant spill to the attended area. This hazard is mainly caused by radioactive polonium aerosols in the air of working area and contamination of surfaces as a result of aerosol precipitation or contact transfer of alpha-activity. To substantiate radiation safety and forecast the aftermath of such accidents is essential to develop a model of polonium activity migration through the first circuit in normal operation and under condition resulting in accidents. The model must be tested by experimental date. Polonium activity release from HLMC into gas is the main element of this model. Russia has almost forty-year experience of operating lead-bismuth cooled reactors of nuclear submarines and on-ground prototypes. The main organizational and technological measures were developed for staff protection against polonium radiation in case scheduled work carrying-out or coolant spill accident. The processes of polonium activity migration through primary circuit of lead-bismuth cooled reactor are described in the paper. A probable danger of polonium activity release in reactor compartment is considered. The developed measures and staff-protection means are presented.
Keywords
lead-bismuth coolant, polonium activity, lead polonide, polonium thermodinamic activity coefficient, effective vapour pressure, release into gaseouse phase, calculated and experimental date comparison, polonium hazard by reactor operation, staff-protection means
Article Text (PDF, in Russian)
References
- Handbook on Lead-Bismuth Eutectic Alloy and Lead Properties, Material Compatibility, Thermal-hydraulics and Technologies. 2015 Edition. NEA. No. 7268. Issy-les-Moulineaux, France: OECD, 2015. 950 p.
- Ausländer J.S., Georgescu I.I. Proceeding of the 1st Int. Conf. Peacefull Using Atomic Energy. Geneva, 1955, vol. 7, p. 389.
- Brooks L.S. The Vapoor Pressure of Polonium. J. Am. Chem. Soc., 1955, vol. 77, p. 3211.
- Abakumov A.S., Ershova Z.V. Uprugost' para poloniya i polonida svintsa [Vapor Tension of Polonium and Lead Polonide]. Radiokhimiya – Radiochemistry, 1974, vol. 6, pp. 396–401.
- Feuerstein H., Oshinski J., Horn S. Behavior of Po-210 in molten Pb-17Li. JNM, 1992, vol. 191–194, рp. 288–291.
- Tupper R.B., Minushkin B., Peters F.E., Kardos Z.L. Polonium Hazards Associated With Lead Bismuth Used as a Reactor Coolant. Proc. of International Conference on Fast Reactors and Related Fuel Cycles. Current Status and Innovations Leading to Promising Plants. Kyoto, Japan, Oct. 28–Nov. 1, 1991, vol. IV, p. P5.6-1-6.9.
- Fisicheskie velichiny. Spravochnik. Pod red. Grigor'yeva I.S., Meylikhova E.Z. [The physical quantities. Handbook. Ed. Grigor’ev I.S., Meylikhov E.Z.]. Moscow, Energoatomizdat Publ., 1991. P. 1034.
- Eichler B. Die Flüchtigkeitseigenschaften des Poloniums. PSI-Report Nr. 02-12. June 2002.
- Gonchar N.I., Pankratov D.V. Opredeleniye kharakteristik vykhoda poloniya v gazovuyu fazu po eksperimental'nym dannym GNTS RF – FEI [Defining Parameters of Polonium Release From HLMC Into Gas Derived From IPPE Experimental Data]. Izvestiya vuzov. Yadernaya Energetika, 2014, no. 1,
pp. 215–221.
- Ohno S., Kurata Y., Miyhara S., Katsura R., Yoshida S. Equilibrium Evaporation Behavior of Polonium and Its Homologue Tellurium in Liquid Lead-Bismuth Eutectic. Journal of Nuclear Science and Technology, 2006, vol. 43, no. 11, pp. 1359–1369.
- Buongiorno J., Larson C. and Czerwinski K.R. Speciation of polonium released from molten lead bismuth. Radiochimica Acta, 2003, vol. 91, no. 3, pp. 153–158. DOI: https://doi.org/10.1524/ract.91.3.153.19984.
- Neuhausen Jörg, Köster U. and Eichler B. “Investigation of evaporation characteristics of polonium and its lighter homologues selenium and tellurium from liquid Pb-Bi-eutecticum”. Radiochimica Acta, 2004, vol. 2, no. 12, pp. 917–923. DOI: https://doi.org/10.1524/ract.92.12.917.55105.
- Witteman W.G., Giorgy A.L., Vier D.T. The Preparation and Idenfication of Some Intermetallic Compounds of Polonium. J. Phys. Chem., 1960, vol. 64, isuue 4, p. 434.
- Petryanov I.V., Borisov N.B., Churkin S.L., Borisova L.I., Starostina I.A. Obrazovaniye i vydeleniye gazoobraznoy fraktsii poloniya iz yego tverdykh preparatov [Formation and Release of Polonium Gaseous Compound from Solid Prepapations One]. Doklady AN SSSR – Reports of USSR Acad. Sci., 1992, vol. 322, no. 3.
- Ampelogova N.I. Radiokhimiya poloniya [Polonium Radiochemistry]. Moskow, Atomizdat Publ., 1976. P. 13.
- Normy radiatsionnoy bezopasnosti NRB-99/2009 [Radiation Safety Norms NRB-99/2009].
- Gromov B.F., Grigir’ev O.G., Dedoul A.V., Toshinsky G.I., Stepanov V.S., Nikitin L.B. Analiz opyta ekspluatatsii reaktornykh ustanovok s teplonositelem svinets-vismut i imevshikh mesto avariy [The Analysis of Lead-Bismuth Cooled Reactors Experience and Occured Accidents]. Sb. dokladov konferentsii “Tyazholyye zhidkometallicheskiye teplonositeli v yadernykh tekhnologiyakh” [Proc. of the Conf. “Heavy Liquid Metal Coolant in Nuclear Technologies”]. Obninsk, IPPE, 1999, vol. 1, p. 63.
- Pankratov D.V., Yefimov E.I., Bolkhovitiniv V.N., Kuranov V.D., Bugreev M.N. Problema poloniya v yadernykh energeticheskikh ustanovkakh so svintsovo-vismutovym teplonositelem [Polonium Problem for Nuclear Power Plant with Lead-Bismuth Coolant]. Sb. dokladov konferentsii “Tyazholyye zhidkometallicheskiye teplonositeli v yadernykh tekhnologiyakh” [Proc. of the Conf. “Heavy Liquid Metal Coolant in Nuclear Technologies”]. Obninsk, IPPE, 1999, vol. 1, p. 107.
- Laurie D. Wiggs, Carol A. Cox-De Vore and George L. Voelz. Mortality among a Cohort of Workers Monitored for Po-210 Explosure: 1944–1972. Epidemiology Section Occupational Medicine Group. Los-Alamos National Laboratory. Health Physics, 1991, vol. 61, no. 1, pp. 71–76.
UDC 621.039.534.6:669.774
Problems of Atomic Science and Technology. Series: Nuclear and Reactor Constants, 2024, no. 4, 4:12